Colourful Solutions > Electron-pair sharing reactions > Coordinate bonds

When a Lewis base reacts with a Lewis acid, a coordination bond is formed. Nucleophiles are Lewis bases and electrophiles are Lewis acids. (HL)

Syllabus reference R3.4.7

Reactivity 3.4.7 - When a Lewis base reacts with a Lewis acid, a coordination bond is formed. Nucleophiles are Lewis bases and electrophiles are Lewis acids. (HL)

  • Draw and interpret Lewis formulas of reactants and products to show coordination bond formation in Lewis acid–base reactions.

Guidance

Tools and links

  • Structure 2.2 - Do coordination bonds have any different properties from other covalent bonds?

The coordinate bond

The coordinate bond, also called a dative (from the latin, meaning "given") is formed when both of the bonding electrons originate on the same atom.

It is important to appreciate that there is no difference between a coordinate bond and a normal covalent bond in terms of bond length and strength, or bonding mechanism as they are both identical - a pair of electrons attracting two nuclear centres.

The ONLY difference between a coordinate bond and a covalent bond is the origin of the electron pair.


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