Which factors contribute to the boiling point of ethanoic acid?

Boiling points are a function of the intermolecular forces.

The ethanoic acid dimer has an effective RMM = 120. This means that considerable Van der Waals force would be expected between particles. Compare with a totally non-polar molecule with a similar relative mass such as decane. The boiling point of decane is 174ºC.

Were ethanoic acid simple monomers (RMM = 60) then comparison with pentane (bp=36ºC) suggests a much higher degree of intermolecular force.

It seems that the boiling point of ethanoic acid (118ºC) is somewhere between that expected from a simple monomer (with hydrogen bonds) and a dimer.

Clearly the situation is not simple and there will be contributions from hydrogen bonding, Van der Waals forces, monomers and dimers. It is difficult to state categorically which is the most important.


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