Colourful Solutions > How much? The amount of chemical change > Chemical equations

The Mad Science Lab

Standard level

In chemical processes the ratio of reacting particles is always fixed for a specific reaction.

Once the number of particles of any component of a known reaction is determined, it is possible to find the number of particles involved of any other component by using the stoichoimetry of the equation.

Syllabus ref: R2.1.1

Reactivity 2.1.1 - Chemical equations show the ratio of reactants and products in a reaction.

  • Deduce chemical equations when reactants and products are specified.

Guidance

  • Include the use of state symbols in chemical equations.

Tools and links


Word equations

Word equations simply show the names of the reacting chemical and products. They are of limited use except for giving an overall description of the chemical reaction. They give no indication of the relative amounts of the reactants or products involved.

Sodium hydroxide + sulfuric acid sodium sulfate + water

To make equations useful, they must show the individual formulae of the reactants and products and indicate the relative quantities in which they react. These 'formula equations' are dealt with below.


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Formula equations and coefficients

Formula equations show the formulae of the reactants and the products on either side. Balancing numbers are used - called the coefficients of the reaction - to ensure that the numbers of particles on both sides of the equation are equal.

In this equation one nitrogen molecule is needed to react with every three hydrogen molecules to produce 2 molecules of ammonia. The coefficient of nitrogen is 1, that of hydrogen is 3, and that of ammonia is 2.

To balance a chemical equation it is important to remember that the formula of the reactants and products cannot be changed and that coefficients may only be placed before the formulae, multiplying them by whole numbers.

Example: One stage in the manufacture of nitric acid is the oxidation of ammonia, as shown below:

4NH3 + _O2 _NO + _H2O

What is the coefficient for O2 when the equation is balanced?

Solution:

Balance the nitrogen by counting up the nitrogen atoms on both sides: 4NH3 + _O2 4NO + _H2O

Balance the hydrogen atoms: 4NH3 + _O2 4NO + 6H2O

Now balance the oxygen atoms: 4NH3 + 5O2 4NO + 6H2O

Correct response : Coefficient = 5

These show the actual numbers of reacting particles in a chemical reaction. The reaction must be BALANCED to give the correct number of particles on each side of the reaction arrow.

2NaOH + H2SO4 Na2SO4 + 2H2O

These equations are constructed by writing the formula of each of the compounds in the reaction, and then by counting up the number of atoms on each side to make sure they are equal. If they are not equal, balancing numbers (coefficients) are added in front of each chemical formula (where needed), so that the numbers of each type of particle on each side of the equation are the same

Step 1 - write the chemical equation

ammonia + oxygen nitrogen monoxide + water

Step 2 - write the formula of each of the reaction components

ammonia + oxygen nitrogen monoxide + water
NH3 + O2 NO + H2O

Step 3 - add coefficients IN FRONT OF the formulae to balance the equation

4NH3 + 5O2 4NO + 6H2O

Note Whenever an exam question asks for an equation, it is the balanced formula equation that is required, unless specified otherwise.


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Ionic equations

When ionic solutions react, the reaction only usually involves some of the ions and not others. An ionic equation shows just the ions implicated in the reaction. The other ions are often called "spectator ions".

2NaOH + H2SO4 Na2SO4 + 2H2O

The ionic equation is written as:

H+ + OH- H2O

Although the formula equation represents the overall process, the sodium ions start off in solution as Na+(aq) and at the end of the reaction they are still Na+(aq), nothing has changed, they are merely spectator ions.

The same applies to the sulfate ions, SO42-. The only particles that actually react are the OH- ions from the sodium hydroxide and the H+ ions from the sulfuric acid.


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State symbols

These are used to show the states of the various compounds that constitute the equation for the reaction.

(s) means that the compound is in the solid state.

(l) means that the compound is in the liquid state.

(g) means that the compound is in the gaseous state.

(aq) means that the compound is dissolved in water, i.e. it is in solution.

2NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l)

The sodium hydroxide and the sulfuric acid are in solution. These make sodium sulfate in solution and water liquid.


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Worked examples

Q334-01 When the following equation is correctly balanced what is the coefficient for O2?

C4H10 + O2 CO2 + H2O
  1. 9
  2. 13
  3. 18
  4. 24
Answer

Balance the carbon - C4H10 + O2 4CO2 + H2O

Balance the hydrogen - C4H10 + O2 4CO2 + 5H2O

Now balace the oxygen - C4H10 + 13/2O2 4CO2 + 5H2O

fractions are not allowed in the correctly balanced equation so multiply through by 2 to remove the fraction.

2C4H10 + 13O2 8CO2 + 10H2O

Response B: Coefficient = 13


Q334-02 When the following equation is balanced, what is the coefficient for oxygen?

_C2H2(g) + _O2(g) _CO2(g) + _H2O(g)
  1. 2
  2. 3
  3. 4
  4. 5
Answer

First balance the carbon

_C2H2(g) + _O2(g) 2CO2(g) + _H2O(g)

Then the hydrogen

_C2H2(g) + _O2(g) 2CO2(g) + 1H2O(g)

However there are now an odd number of oxygen atoms. This will not make a whole number of O2 molecules. Therefore the whole equation must be multiplied through by 2.

2C2H2(g) + _O2(g) 4CO2(g) + 2H2O(g)

Now balance the oxygen atoms

2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(g)

Response D: 5 x O2


Q334-03 Hydrogen sulfide, H2S, reacts with oxygen to form sulfur dioxide and water as shown below:
2H2S + _O2 _SO2 +_H2O

What is the whole number coefficient for oxygen when this equation is balanced?

  1. 1
  2. 2
  3. 3
  4. 6

Answer

Balance the sulfur

2H2S + _O22SO2 +_H2O

Then balance the hydrogen

2H2S + _O22SO2 + 2H2O

Now work backwards and balance the oxygen

2H2S + 3O22SO2 + 2H2O

Response C: 3 moles of oxygen


Q334-04 When this equation:
wC4H9OH + xO2 yCO2 + zH2O

is balanced correctly the coefficient, x, for O2 is:

  1. 6
  2. 9
  3. 13/2
  4. 13

Answer

Assume w = 1, balance the carbon atoms:

C4H9OH + xO24CO2 + zH2O

balance the hydrogen atoms

C4H9OH + xO24CO2 + 5H2O

Balance the oxygen atoms, do not forget the oxygen atom in the butanol:

C4H9OH + 6O24CO2 + 5H2O

Response A : 6


Q334-05 The reaction of lead(II) sulfide with oxygen at high temperature is represented by the unbalanced equation:
PbS(s) + O2(g)PbO(s) + SO2(g)

What is the sum of the coefficents in the balanced equation?

  1. 5
  2. 9
  3. 8
  4. 13

Answer

Inspection of the equation shows that the Pb and the S are balanced, but the oxygen atoms are unbalanced.

The right hand side must provide an even number of oxygen atoms while maintaining the coefficients of PbO(s) and SO2(g) equal.

Double the right hand side:

PbS(s) + O2(g) 2PbO(s) + 2SO2(g)

Now balance the PbS(s) and the O2(g)

2PbS(s) + 3O2(g) 2PbO(s) + 2SO2(g)

Response B : sum of coefficients = 9


Q334-06 The oxidation of nitrogen monoxide can be represented by the word equation:
nitrogen monoxide + oxygen nitrogen dioxide

Write out the balanced equation.

Answer

First write down the formulae for each component of the reaction

NO + O2 NO2

Now inspect the number of atoms on either side. There are three oxygen atoms on the left and only two on the right. Multiply the NO by 2 and the NO2 by 2

2NO + O2 2NO2

The equation is balanced!


Q334-07 White phosphorus is manufactured by heating phosphate ore with sand and coke in an electric furnace at 1500ºC. The phosphorus(V) oxide, initially formed in an inert atmosphere of carbon monoxide, is then reduced by the coketo phosphorus. The first stage in the process may be represented by the unbalanced equation.
Ca3(PO4)2 + SiO2 CaSiO3 + P4O10

What is the coefficient for silicon dioxide when the equation is correctly balanced?

Answer

From the equation: Ca3(PO4)2 + SiO2 CaSiO3 + P4O10

It may be seen that all of the phosphorus atoms from the calcium phosphate end up in the phosphorus pentoxide.

Therefore the coefficient for Ca3(PO4)2 must be 2 and working forwards the coefficient for CaSiO3 must be 6 to equalise the calcium atoms on both sides.

2Ca3(PO4)2 + SiO2 6CaSiO3 + P4O10

Working backwards then the coefficient for the SiO2 must also be = 6

2Ca3(PO4)2 + 6SiO2 6CaSiO3 + P4O10


Q334-08 When the following equation is correctly balanced what is the coefficient for oxygen?
C6H6 + O2 CO2 + H2O
Answer

From the equation: C6H6 + O2 CO2 + H2O

6 carbon atoms in the benzene must make 6 carbon dioxide molecules

C6H6 + O2 6CO2 + H2O

And 6 hydrogen atoms from the benzene must produce 3 water molecules

C6H6 + O2 6CO2 + 3H2O

Counting back the oxygens on the right hand side = 15. This would make an odd number of O2 molecules so the whole eqation must be mutiplied by 2

2C6H6 + O2 12CO2 + 6H2O

Now there are 30 oxygen atoms on the right hand side = 15 x O2 molecules, giving

2C6H6 + 15O2 12CO2 + 6H2O

Therefore the coefficient for oxygen = 15


Q334-09 When the following equation is correctly balanced what is the coefficient for potassium chlorate(V)?
KClO3 KClO4 + KCl
Answer

By inspection of the equation: KClO3 KClO4 + KCl

It may be seen that the oxygen atoms must be equalised. They only occur in two compounds therefore mutiplying each by its opposite number of oxygens makes them equal, i.e mutiply KClO3 by 4, and KClO4 by 3.

4KClO3 3KClO4 + KCl

The equation is now balanced so the coefficient for potassium chlorate (V) = 4


Q334-10 In the manufacture of antimony, the sulfide ore is roasted in oxygen to produce antimony oxide according to the unbalanced equation:
Sb2S3 + O2 SO2 + Sb2O3

What is the coefficient for oxygen when the equation is correctly balanced?

Answer

Inspection of the equation: Sb2S3 + O2 SO2 + Sb2O3

Shows us that all of the sulfur in the antimony sulfide Sb2S3 turns to sulfur dioxide SO2

Sb2S3 + O2 3SO2 + Sb2O3

There are now 9 x oxgen atoms on the right hand side - an odd number so the equation must be multiplied by 2

2Sb2S3 + O2 6SO2 + 2Sb2O3

now there are 18 oxygen atoms on the right hand side = 9 x O2 molecules

2Sb2S3 + 9O2 6SO2 + 2Sb2O3

Therefore the coefficient for oxygen = 9


Q334-11 Write an equation to represent the following reaction:
sodium + oxygen sodium oxide
Answer

Step 2: write down the symbols for each component of the equation

Na + O2 Na2O

Step 3: balance the numbers of atoms on either side of the arrow

4Na + O2 2Na2O


Q334-12 Write a formula equation to represent the following reaction:
sodium carbonate + hydrochloric acid sodium chloride + carbon dioxide + water
Answer

Step 2: write down the symbols for each component of the equation

Na2CO3 + HCl NaCl + CO2 + H2O

Step 3: balance the numbers of atoms on either side of the arrow

Na2CO3 + 2HCl 2NaCl + CO2 + H2O


Q334-13 Write an equation to represent the following decomposition:
Calcium nitrate calcium oxide + nitrogen dioxide + oxygen
Answer

Step 2: write down the symbols for each component of the equation

Ca(NO3)2 CaO + NO2 + O2

Step 3: balance the numbers of atoms on either side of the arrow

2Ca(NO3)2 2CaO + 4NO2 + O2


Q334-14 Write an equation to represent the following neutralisation:
Calcium hydroxide + hydrochloric acid calcium chloride + water
Answer

Step 2: write down the symbols for each component of the equation

Ca(OH)2 + HCl CaCl2 + H2O

Step 3: balance the numbers of atoms on either side of the arrow

Ca(OH)2 + 2HCl CaCl2 + 2H2O


Q334-15 Write an equation to represent the following synthesis reaction:
Iron + chlorine iron(III) chloride
Answer

Step 2: write down the symbols for each component of the equation

Fe + Cl2 FeCl3

Step 3: balance the numbers of atoms on either side of the arrow

2Fe + 3Cl2 2FeCl3


Q334-16 Write the ionic equation for the reaction betweeen sulfuric acid and sodium hydroxide.

Answer

Word equation:

sulfuric acid and sodium hydroxide sodium sulfate + water

formulae:

NaOH(aq) + H2SO4(aq) Na2SO4(aq) + H2O(l)

Balanced:

2NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l)

Here we can see that the sodium ions (Na+) in the sodium hydroxide solution remain as sodium ions in the sodium sulfate solution - they are SPECTATOR IONS.

The same applies to the sulfate ions SO42-. They start off as sulfate ions in the sulfuric acid solution and end up as sulfate ions in the sodium sulfate solution - they are also spectator ions. The only ions that actually react together are the hydrogen ions from the sulfuric acid and the hydroxide ions from the sodium hydroxide:

H+(aq) + OH-(aq) H2O(l)


Q334-17 Write an ionic equation for the reaction between silver nitrate and sodium chloride forming a white silver chloride precipitate.

Answer

Word equation:

silver nitrate + sodium chloride sodium nitrate + silver chloride

formulae:

AgNO3(aq) + NaCl(aq) NaNO3(aq) + AgCl(s)

Already balanced:

Here we can see that the silver chloride is formed as a solid precipitate. These ions must then be removed from the solution. All of the other ions remain behind as spectator ions in solution

Ag+(aq) + Cl-(aq) AgCl(s)


Q334-18 Write an ionic equation to represent the reaction between barium chloride and magnesium sulfate

Answer


Barium chloride and sodium sulfate react together to form a precipitate of barium sulfate - this is used to identify the sulfate group.

The unbalanced equation

BaCl2(aq) + Na2SO4(aq) BaSO4(s) + NaCl(aq)

balanced

BaCl2(aq) + Na2SO4(aq) BaSO4(s) + 2NaCl(aq)

BUT, the sodium chloride is still in solution so its ions have not reacted.

The only ions involved in reaction are those that come together to make the precipitate:

Ba2+(aq) + SO34-(aq) BaSO4(s)


Q334-19 Write an ionic equation to represent the reaction between iron(III) sulfate and sodium hydroxide

Answer

iron(III) sulfate and sodium hydroxide react together to form a precipitate of iron(III) hydroxide - this is used to identify the iron(III) ion.

The unbalanced equation

NaOH(aq) + Fe2(SO4)3(aq) Na2SO4(aq) + Fe(OH)3(s)

balanced

6NaOH(aq) + Fe2(SO4)3(aq) 3Na2SO4(aq) + 2Fe(OH)3(s)

BUT, the sodium ions have not reacted and neither have the sulfate ions - the sodium sulfate 'produced' is in solution.

The only ions involved in reaction are those that come together to make the precipitate:

Fe3+(aq) + 3OH-(aq) Fe(OH)3(s)


Q334-20 Write an ionic equation for the reaction between manganese(IV) oxide and hydrochloric acid.

Answer

This is the reaction used to prepare chlorine in the laboratory:

manganese(IV) oxide and hydrochloric acid manganese(II) chloride + chlorine + water

The balanced equation:

MnO2(s) + 4HCl(aq) MnCl2(aq) + Cl2(g) + 2H2O(l)

Two of the chloride ions from the left hand side are spectator ions whereas all of the other ions are involved in reaction:

MnO2(s) + 4H+(aq) + 2Cl-(aq) Mn2+(aq) + Cl2(g) + 2H2O(l)

If you check out the charge totals on both sides it may be seen that they are equal.


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Now test yourself

Exercise 334 - Balancing equations
Your answer   Questions Correct

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